Calculating Enthalpy Changes Using Hesss Law

Calculating Enthalpy Changes Using Hess's Law Hesss Law, also known as Hesss Law of Constant Heat Summation, states that the total enthalpy of a chemical reaction is the sum of the enthalpy changes for the steps of the reaction. Therefore, you can find enthalpy change by breaking a reaction into component steps that have known enthalpy values. This example problem demonstrates strategies for  how to use Hesss Law to find the enthalpy change of a reaction using enthalpy data from similar reactions. Hess's Law Enthalpy Change Problem What is the value for ΔH for the following reaction?CS2(l) 3 O2(g) → CO2(g) 2 SO2(g)Given:C(s) O2(g) → CO2(g); ΔHf -393.5 kJ/molS(s) O2(g) → SO2(g); ΔHf -296.8 kJ/molC(s) 2 S(s) → CS2(l); ΔHf 87.9 kJ/mol Solution Hesss law says the total enthalpy change does not rely on the path taken from beginning to end. Enthalpy can be calculated in one grand step or multiple smaller steps.To solve this type of problem, we need to organize the given chemical reactions where the total effect yields the reaction needed. There are a few rules that must be followed when manipulating a reaction. The reaction can be reversed. This will change the sign of ΔHf.The reaction can be multiplied by a constant. The value of ΔHf must be multiplied by the same constant.Any combination of the first two rules may be used. Finding a correct path is different for each Hesss law problem and may require some trial and error. A good place to start is to find one of the reactants or products where there is only one mole in the reaction.We need one CO2, and the first reaction has one CO2 on the product side.C(s) O2(g) → CO2(g), ΔHf -393.5 kJ/molThis gives us the CO2 we need on the product side and one of the O2 moles we need on the reactant side.To get two more O2 moles, use the second equation and multiply it by two. Remember to multiply the ΔHf by two as well.2 S(s) 2 O2(g) → 2 SO2(g), ΔHf 2(-326.8 kJ/mol)Now we have two extra S and one extra C molecule on the reactant side we dont need. The third reaction also has two S and one C on the reactant side. Reverse this reaction to bring the molecules to the product side. Remember to change the sign on ΔHf.CS2(l) → C(s) 2 S(s), ΔHf -87.9 kJ/molWhen all three reactions are added, the extra two sulfur and one extra c arbon atoms are canceled out, leaving the target reaction. All that remains is adding up the values of ΔHf.ΔH -393.5 kJ/mol 2(-296.8 kJ/mol) (-87.9 kJ/mol)ΔH -393.5 kJ/mol - 593.6 kJ/mol - 87.9 kJ/molΔH -1075.0 kJ/molAnswer:  The change in enthalpy for the reaction is -1075.0 kJ/mol. Facts About Hess's Law Hesss Law takes its name from Russian chemist and physician Germain Hess. Hess investigated thermochemistry and published his law of thermochemistry in 1840.To apply Hesss Law, all of the component steps of a chemical reaction need to occur at the same temperature.Hesss Law may be used to calculate  entropy and Gibbs energy in addition to enthalpy.

Quotes of Encouragement for Women

Quotes of Encouragement for Women Fight off the feeling of helplessness. You are a woman! You have the power to create, nurture, and mold. Your voice may be soft, but it carries a sense of determination. Your shoulders may be delicate, but they can carry the burden of a family with ease. Dont underestimate your strengths and abilities. When the time is right, you can prove your mettle to the world. Quotes of Encouragement for Women Read these encouraging quotes for women and learn to believe in yourself. These quotes can help you overcome any challenge that hinders your growth. St. Teresa of AvilaHowever softly we speak, God is near enough to hear us. Anais NinThere came a time when the risk to remain tight in the bud was more painful than the risk it took to blossom. Havelock EllisCharm is a womans strength just as strength is a mans charm. Indira GandhiPeople with clenched fists can not shake hands. Alice WalkerThe most common way people give up their power is by thinking they dont have any. Anais NinDreams are necessary to life. Pearl BaileyPeople see God every day. They just dont recognize him. Diane MariechildA woman is the full circle. Within her is the power to create, nurture and transform. Grandma MosesLife is what we make it, always has been, always will be. Edgar Watson HoweA man has his clothes made to fit him; a woman makes herself fit her clothes.

Website Design. User Experience and Usability Essay

Website Design. User Experience and Usability - Essay Example 4). Interaction design is likewise defined as an aesthetic facilitation between human beings and products or services that are perceived with certain ‘awareness’ due to the microprocessors that can sense and respond to tabs and keys used as prompts and commands (Saffers, 2007, p. 4). Being engineered to respond to human beings, there are embed rules, methods, and scientific contextual nuances targeted at responding to problems and circumstances (Saffers, 2007, p. 4). With the recent influx of collaborative media, information technology and its software become essential in practicing ‘digitally mediated practices’ through collaborative action based on â€Å"cross-medial infrastructures (Parviainen, Tuuri, & Pirhunen, 2013, p. 103).† Computers for instance became more functional and have increasing became a necessity for daily use because it is engineered with disciplined design, structures, and communicative processes that are truly instrumental for in teraction and for online discourse (Parviainen et.al., 2013, p. 103). This is developed by people who invented interactive technology to hasten the â€Å"reduction of physical action and cognitive load of users (Lowgren & Reimer, 2013, p. 86).† ... ion technology-dependent persons because ideas evolved into digitized realities that have seemingly traced realities into digital forms (Moggridge, 2006, p. 1). Such is significant because it has scaled up entrepreneurial design for the development of technology (Moggridge, 2006, p. 1). For instance, a person, as a user of computer and or of the online social network, or of software programs embed in it will certainly be able to appreciate it when user is able to read and understand the methods and its application. These logical systems and methods or approaches must be read well to fully enjoy its functionality. Gube (2010) explained that user experience refer to the interfacing of system or a website generally detailing on human-computer interaction (p. 1). At its maximum, a tech experience can appreciate its utility if the technology can interact with human factors, produce accessibility, make use of it for marketing, do ergonomics and bolster system performance (Gube, 2010, p. 1) . As such, the web can be valued of its efficiency, services and creative functionalities (Gube, 2010, p. 1). Must be user-centered Gube (2010) asserted that the web engineering must be user-centered or must be tailored sensitively in accordance to the needs of the users or subscribers (p. 1). Gube (2010) defined user-centered design as technological architecture that is design to fit to the needs of users (p. 1). Business experts contended that a product can only jibed with utilitarian value when products are developed to answer the needs of clients or the market (Gube, 2010, p. 1). The sales of these goods cannot be appreciated when it lacks value and is bereft of meaning for clients (Gube, 2010, p. 1). That’s why technologies these days are modelled by its usefulness, multi-tasks

Communications Analysis of two interviews Essay

Communications Analysis of two interviews - Essay Example Besides, there was another Loan officer that interrupted out discussion quite frequently during the interview. Although I did not express it, yet somewhere deep inside me, I had mixed feelings about this attitude of Bill Cook and his staff. Opening and Closing: In the beginning, Bill Cook welcomed me into his room with a big smile on his face. We wished each other and shook hands. He himself took my coat and pulled back a chair for me. He asked me if I would like to have something to drink first. Despite his professionalism and nice tone of speech, I remained quite intimidated throughout the interview. By the time we were done with the interview, we shook hands with each other once again, and I thanked him for his time, attention and consideration. Relationship Dimensions: I felt quite nervous throughout the interview. Bill Cook was a stranger to me. We had never seen each other before the interview. In order to get the maximum response to my questions, I had to make my questions eas ily perceivable for Bill Cook. This demanded development of a comfort level with a person, who was an altogether stranger to me, though I managed to develop it sufficiently well. However, there was so much to ask that I felt constant nervousness. I had to ask Bill Cook why women Loan Officers could not be seen at any of the Land Bank branches. This and several other questions like this were indeed, quite personal, yet they were extremely important, so could not be missed. The nervousness kept me from becoming over confident and I conducted the interview in a prudent manner. At the end of the interview, the atmosphere was calm and relaxed and we had both enjoyed the discussion. Listening: Bill cook was a little preoccupied and seemed to be in a hurry from the speed of his response to my questions. Besides, his attention was being constantly sapped by the flooding phone calls and the interruption of the Loan officer, yet he managed to hear me good enough to deliver to the point answer s. In order to make my self heard well, I made use of the aggressive listening approach, and from the results, I can tell that the selection was right. Nonverbal communication: I was dressed in a business black suit and blazer and Bill Cook had worn khaki’s and a striped polo shirt. Bill Cook made good use of body language in conveying his points to me. He particularly emphasized upon the use of hands and eyes while making the speech. He maintained a constant and uninterrupted eye contact with me. I could not stand that, and would occasionally look down in an attempt to hide my nervousness and intimidation that had occupied me throughout the interview. Bill Cook tried to explain with hands, which made more comfortable and facilitated while making the speech. A hand shake was a good symbol of nonverbal greeting both before and after the interview. Reflection on the interview: Overall, the interview went extremely fine. I do believe that I could somehow, not get the entire trut h from Bill Cook regarding the lack of women’s representation in the job. Perhaps, I should have pressed him harder on the subject, though it was not entirely possible because Bill Cook seemed to be in too much a hurry to let me play with words. Still, I got sufficient information from Bill Cook to content my concerns. I chose to interview Bill Cook because he is quite experienced in Loan banking. I wanted to learn about banking and wanted to know why women did not participate in it in any branch of the

The Catcher In The Rye :: essays research papers

  Ã‚  Ã‚  Ã‚  Ã‚  The novel The Catcher in the Rye, by J.D. Salinger, is about a troubled young man named Holden Caulfield. Holden searches his teenage life, struggling to find answers to his questions about himself and his identity. No matter where Holden goes, in his opinion he is surrounded by phonies. They appear to be everywhere Holden is: his school, the hotel, the theatre, and all over the streets of New York. The story is told from Holden’s point of view, as he endeavours to put together the pieces of the puzzle that he calls his life.   Ã‚  Ã‚  Ã‚  Ã‚  Holden Caulfield, the main character in the novel, is an immature teenager. Holden is sixteen years old, six feet two inches tall, with a crew cut and prematurely greying hair. His story begins as he is kicked out of prep school, and takes off to New York. Holden's thoughts and ideas reveal many of his character traits. One late Saturday night, four days before the beginning of school vacation, Holden decides to leave Pencey, his school, at once and travels to New York by train. Once in New York, he decides that he will stay in a cheap motel until Wednesday, when he is to return home. His plan shows how very impetuous he is and how he acts on a whim. He is unrealistic, thinking that he has a foolproof plan, even though the extent of his plans are to â€Å"take a room in a hotel...and just take it easy till Wednesday.† This course of action proves Holden’s recklessness and immaturity very early on in the novel.   Ã‚  Ã‚  Ã‚  Ã‚  Another considerably minor (and yet still imperative) addition to the novel is Phoebe Caulfield. Holden’s younger sister is his main supporter. She sticks with him no matter what, but she also, however, is not afraid to scold Holden for his errors. Although Phoebe is merely a young child, she understands Holden, sometimes more than he does. â€Å"Old Phoebe didn’t say anything, but she was listening.... she always listens when you tell her something. And the funny part is she knows, half the time, what the hell you’re talking about. She really does.† (167) Phoebe is an instant reminder of delight to Holden, and every decision he makes revolves somehow around the sister he loves so much.   Ã‚  Ã‚  Ã‚  Ã‚   Holden Caulfield, at first, appears to be having a conflict with society, but, upon closer examination, we see that he is truly only at war with himself.

Global Ethical Position Of Bp Commerce Essay

In a 2006 interview with ProPublica after the Prudhoe Bay spill, published in Fortune BPs main executive of American operations, Robert Malone, said â€Å" There is no uncertainty in my head, what happened may non hold broken the jurisprudence but it broke our values. Corporate societal duty is merely a responsibility of attention which an administration owes to its stakeholders and the environment in which it operates. Hodgetts et at ( 2006, p65 ) states that: â€Å" Corporate societal duty ( CSR ) can be defined as the actions of a house to profit society beyond the demands of the jurisprudence and the direct involvements of the house. Pressure for greater attending to CSR has emanated from a scope of stakeholders, including civil society ( the wide societal involvements in a given part or state ) and from nongovernmental administrations ( NGOs ) . These groups have urged MNCs to be more antiphonal to the scope of societal demands in developing states, including turn toing concerns about working conditions in mills or service centres and go toing to the environmental impacts of their activities. † Harmonizing to Stewart Broome the Director of Business Ethical motives at BP, BP operate under planetary criterions through its usage of advanced engineering, safe working conditions and operational procedures, safer operational patterns for the protection of the environment in conformity with planetary ethical criterions. However, contrary to BP ‘s ethical place the undermentioned incidents have occurred within the last five old ages which resulted in the loss of lives, devastation of the environment, and marine life.Lustgarten ( 2010 ) reported that:A BP ‘s refinery explored in Texas, March 2005 this resulted in the decease of 15 workers and the hurt of 170 others. Probes determined that BP ignored its ain protocols in the operation of the tower and that the company ‘s warning system was besides disabled. BP accordingly pleaded guilty to federal felony charges and was fined more that $ 50 million by the US Environmental Protection Agency. One twelvemonth subsequently 4,800 barrels of oil leaked into the Alaskan snow through a hole in the company ‘s grapevine at Prudhoe Bay. It was reported by Fortune that BP failed to look into the grapevine in 2002 even though they had been cautioned to look into the grapevine in 2002, they failed to make so. As a consequence a $ 12 million mulct was imposed on BP for a misdemeanor misdemeanor of the federal Water Pollution Control Act. It was subsequently determined by a Congress commission, that BP had ignored chances to forestall the spill and that â€Å" Draconian † cost-saving steps had led to short cuts in its operational projects. BP ‘s most recent incident, on the 20 April 2010 what was confirmed sealed on 19 September 2010 resulted in the decease of 11 individuals. Though the company has investigated the possible causes of the oil spill on the Gulf of Mexico given its path record in the yesteryear there is a deficiency of warrant that such calamities would non go on once more. The households of the workers who died have filed cases impeaching BP of carelessness. Reviewing BP ‘s operations it appears that BP should revisit its planetary ethical place as it relates to the safety of its work force and the environment. It seems that the proper steps and strategic execution of procedures are non being adhered excessively. BP should take the necessary stairss to guarantee the proper care of rigs, regular wellness and safety preparation of staff, proper care of works and equipment to forestall incidents and accidents.The deductions of their trade name and sellingThe universe over the past 20 old ages or so hold become more environmentally painstaking and caring towards prolonging, continuing and keeping the environment. The BP trade name has been affiliated with saving of the environment. BP.Com stated: â€Å" The systems, criterions and engineerings we apply to minimise our environmental footmark. † In giving its operations to responsible planetary leading the company was able to better its repute and increase its bottom line. As a consequence, BP ‘s fiscal position has been sound as stated by Dailyfinance ( 2010 ) stated: â€Å" Due to higher oil monetary values, BP ‘s first one-fourth 2010 net incomes were $ 6.08 billion compared to $ 2.56 billion in the first one-fourth of 2009. † The BP trade name captured a big portion of the mark market this was a contemplation of the company ‘s success. For 16 back-to-back old ages BP individuality as Amoco was rated the best crude oil trade name by consumers and they besides enjoyed one of the three highest trade name trueness reputes for gasoline in the US this was comparable merely to Chevron and Shell. However, the BP trade name is now perceived as socially and environmentally uncommitted to the planetary environment in which they operate and as a consequence there will be â€Å" fall-out † from the BP trade name and its merchandises. John Kleine executive manager of the BP Amoco Marketers Association ( 2010 ) stated: â€Å" Some BP gas station proprietors in the United States want to drop the BP name and return to the Amoco trade name to retrieve concern hit by public choler over the Gulf of Mexico oil spill catastrophe. The worst seaward oil spill in U.S. history fouled beaches from Texas to Florida, lay waste toing the Gulf seashore fishing and touristry industries. Some environmental groups called for a boycott of BP gas Stationss. † Due the negative impact of that the company ‘s operations has on the environment they are traveling to be individual who would reject the BP trade name. Kleine ( 2010 ) stated: â€Å" The BP spill has had a psychological impact on distributers. He described it as a clip of crisis and triageaˆÂ ¦.That truly comes from being concerned about their concern, their support, their investing, seeing every twenty-four hours the intelligence that would be given to do you believe that the concern is traveling to worsen. † Johansson ( 2006, p11 ) stated that in planetary selling it is indispensable that selling activities are coordinated and integrated across geographical lodgers. Merchandises are standardize, packaging of merchandises are uniformed with indistinguishable stigmatization in a figure of states. JOHANSSON ( 2006, p15 ) states that: â€Å" Global trade names are trade names that are available, good cognize, and extremely regarded throughout the universe ‘s market. Examples include Swatch, Mercedes, Nestle, Coca-Cola, Nike, Mc Donald ‘s, Sony and Honda. † BP can be compared to the instance of planetary company Nike and the allegations of child labor, insecure working conditions and inhumane conditions of work. Though Nike ne'er admitted straight to any incorrect making they did nevertheless, raise the minimal hiring age from 16 to 18 old ages, improved the conditions of work and the company even created a place of a frailty president for corporate and societal duty. The universe may mostly comprehend BP as an irresponsible company non presently taking caring for the environment, its workers and the planetary community at big. BP ‘s company image as it relates to the environment, Marine and wildlife is tainted due to the figure and badness of oil spills, particularly given the length of clip about five months ( September 2010 ) which it took for the well to be sealed. The public appears to hold lost trust and religion in BP ‘s ability to carry on its operations in a mode which is safe for their workers and the environment in which it operates. Non-governmental groups would clamor for stricter control and harsher punishments for companies through their operations. The fishing industry, mostly little concerns, along the seashore expressed concerns that they may be taken for â€Å" a drive † due to BP ‘s hold in covering with their claims for losingss, after what has been considered the worst natural catastrophe in recent times. There is the urgency for stricter statute law by authoritiess which would guarantee that companies that operate in their state follow wellness and safety policies harmonizing to the Occupational Health Safety Act. Failure by any company to implement safer working conditions and operations can merely weaken the company ‘s image and present a menace to the endurance of the company. Persons would seek alternate merchandises and services from other companies which in its production and fabrication phases are non harmful but safer to the environment. PERREAULT ( 2005, p256-257 ) stated that: â€Å" Brand rejection means that possible clients wo n't purchase a trade name unless its image is changed. Rejection may propose a alteration in the merchandise or possibly merely a displacement to aim clients who have a better image of the trade name. Get the better ofing a negative image is hard and can be really expensive. † Global clients dissatisfied with trade name image can ensue in consumers globally rejecting the trade name which would finally impact BP ‘s net incomes.What planetary selling scheme should they follow now?In reappraisal BP has a â€Å" up- hill † conflict to reconstruct its bruised repute through its acceptance of an international civilization of safety for their workers and the environment. Fredrx, ( 2010 ) argues that: â€Å" BP may hold plugged the leak in the Gulf Oil spill, but the harm done to its trade name will take old ages to repair. A new selling industry study released Wednesday shows the British oil company has tumbled off a list of the universe ‘s top 100 trade names. † It is extremely recommended that BP strengthen its trade name unity through corporate societal duty and planetary ethical behaviour, which would pull clients one time once more to the BP trade name. By signaling to its stakeholders it is committed to run intoing its moral duties and outlooks beyond what they are required to make by statute law leting for the buy-in to the BP trade name. It is indispensable at this clip the BP re-strategize its operations to ‘regain ‘ its image of an environmentally friendly â€Å" green † crude oil company. Therefore, it would be prudent for BP to reconstitute the company and its direction construction. Freeman et at ( 2007, 6 ) stated that: ( painstaking trade names, †¦ intend trade names that see socially responsible behavior as an built-in portion of what they do, instead than as an attention deficit disorder on. †¦ .conscientious trade name proprietors are human-centric and transparent, focused on making positive alteration in the universe ( non merely on understating the negatives ) and cognizant of the demands of all stakeholders. † To retrieve rapidly it is of important importance that BP focuses its resources and attending on issues of safety. The assignment of Mr Robert Riley to the place of Head of Safety and Operational Risk, Competency and Capability Development was as a direct consequence of his 10 twelvemonth reign at the caput of BP Trinidad without incidents and accidents. The company wants to further a civilization on nothing accidents in their planetary operations. Paul, ( 2010 ) stated that: â€Å" In this new function Riley will describe to Bly and will take BP ‘s worldwide attempts to develop industry taking quality and rigour into BP ‘s operations, peculiarly as it relates to safety and operational hazard. aˆÂ ¦As a effect of the spill BP established a new Safety and Operation Risk unit to let functionaries to step in in all of BP ‘s proficient activities. † This move was necessary to cover with the concerns from the planetary environment sing the issues of safety in BP ‘s operations which resulted in the oil spill of April 2010. Their purpose is to standardize BP ‘s planetary safety and operational unity to a degree which would extinguish accidents and incidents go forthing negative impacts on the environment. Mr Riley was hence given this assignment to assist reconstruct the image and repute of BP as an environmentally caring company, since Mr Riley while he take BPTT had zero incidents. Johansson ( 2006, p537 ) stated: â€Å" Global public dealingss is a signifier of indirect publicity of merchandises and services that focuses on making good will towards the corporation as a whole. The corporate communications staff at central offices and its opposite number in the assorted host states serve as boosters of the corporation to assorted stakeholders interested in the company ‘s foreign enlargement † It is of import that rigorous policies on the Occupational Health and Safety Act are decently implemented and enforced. The Company ‘s image has to alter reflecting that they are an environmentally painstaking company. Therefore this is an effort by BP to reconstruct its trade name and image. Their image has to alter to one which is socially, ethically and environmentally witting. The spill of April 2010 has surely impacted negatively on BP ‘s image as a â€Å" green † company. It is of import that they return to the company ‘s vision and develop and implement schemes which would enable the company to cover with its image and trade name rebuilding. â€Å" The 1000000s of gallons of oil that have spilled into the Gulf of Mexico are more like an epidemic, one that we will be contending for months and even years.A But do no error: A We will contend this spill with everything we ‘ve got for every bit long as it takes.A We will do BP wage for the harm their company has caused.A And we will make whatever ‘s necessary to assist the Gulf Coast and its people recover from this calamity. † In the wake of the spill it would be advisable to BP to redrand its advancing the â€Å" new † company as a more human-centric and environmental painstaking company. BP would besides be advised to work with its stakeholders to guarantee such a catastrophe ne'er happensAFour possible ethical stance BP can followResearching Corporate Strategy, Seventh Edition A © Pearson Education Ltd 2005Word count: -2049

How And Authority In George Orwells Shooting An Elephant

Our life of various kinds of decisions. Now then, how many times a man faces a difficult situation where he should make a momentous decision? Many times and, unfortunately, sometimes people are forced to do some things that they do not want to do. So, in the essay Shooting an Elephant George Orwell describes on his personal experience how and authority influences people to sacrifice their own principles. I believe that all people need in a harmony with oneself and not bend before others to try to satisfy other peoples needs. Firstly, when I read Orwells work I was really shocked, my feelings were vague like my mind was in a haze. The writer tells about his life back in Burma as a police officer. I felt the struggle because of†¦show more content†¦It was even dangerous for Orwell himself, he was just worried about what he should do not to lose his face in front of people who would laugh at him later. This essay opened my eyes to the peoples obsession with public opinion. People become so pressed that they start satisfy needs of others instead of doing what they really want to do. I remember my high school years very clear and right now I understand that at some points I have experienced this obsession and pressure. When I went to my high school, I was pressured by circumstances. I did not know anyone because it was a new school for me and I had to build relations with teachers and classmates. I was new at my high school, so, I had to be over friendly with people, show teachers that I am a good student and the most important idea that I had to be very quiet and keep my mouth closed. I was quiet because I did not want people to think that I am a white crow. If I think about this situation I see that at least other students had a significance because they were not new at this school and stuff, and teachers – all already knew them and because of this fact my classmates had mor e benefits than I had. Teaches were more willing with help to other students more than help to me because, I believe, they had a prejudice about me and some sort of expectations. At that time at high school I had not been understanding that I almost became a chameleon forShow MoreRelatedThe Evil Of Imperialism In George Orwells Shooting An Elephant1023 Words   |  5 PagesShooting An Elephant In George Orwell’s narrative, â€Å"Shooting An Elephant,† Orwell recreates his experience as a soldier trying to end imperialism in the country of Burma by shooting an elephant. George Orwell recreates this experience of imperialism being evil through the use of literary devices. Orwell opens his essay by reflecting upon the evil of British imperialism before shooting the elephant. 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